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Lattice Energy Calculator

Estimate ionic lattice energy from charges

Lattice Energy Calculator

Lattice energy is the energy released when gaseous ions combine to form a crystalline ionic solid (or equivalently, the energy required to separate the solid into gaseous ions). It measures the strength of ionic bonding.

  1. 1Proportional to |z+||z−|/r (Coulomb's law)
  2. 2|z| = ionic charges · r = sum of ionic radii
  3. 3Higher charges and smaller ions → larger lattice energy
  4. 4Measured experimentally via Born-Haber cycle
NaCl vs MgO comparison=NaCl ≈ −787 kJ/mol · MgO ≈ −3795 kJ/molMgO has 2+ and 2− ions → much larger lattice energy
CompoundLattice energy (kJ/mol)
LiF−1037
NaCl−787
KBr−689
MgO−3795
CaO−3414

Fun Fact

MgO has one of the highest lattice energies of simple binary compounds — which is why magnesium oxide has a melting point of 2,852°C and is used as a refractory material in furnaces.

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