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Crystal field theory explains metal complex color, magnetism, and stability through d-orbital splitting in ligand field.

Guia passo a passo

  1. 1Input metal ion, ligands, geometry
  2. 2Calculate d-orbital splitting energies
  3. 3Predict color and magnetic properties

Exemplos resolvidos

Entrada
[Fe(CN)₆]⁴⁻: strong field, low spin, diamagnetic
Resultado
vs. [Fe(H₂O)₆]²⁺: weak field, high spin, paramagnetic

Erros comuns a evitar

  • Confusing high vs. low spin
  • Not applying to correct geometry

Perguntas frequentes

Why does color depend on coordination?

Different ligand fields cause different d-orbital splittings; visible light absorption matches energy gaps.

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