Molar mass is the mass of one mole of a substance β it bridges the atomic world (amu) and the lab world (grams). Every stoichiometry calculation starts here.
What Is Molar Mass?
Molar mass is numerically equal to the atomic mass of an element or the sum of atomic masses in a compound, expressed in grams per mole (g/mol).
The key: the atomic mass on the periodic table (in amu) equals the molar mass (in g/mol).
- Carbon (C): atomic mass = 12.011 amu β molar mass = 12.011 g/mol
- Oxygen (O): 15.999 g/mol
- Hydrogen (H): 1.008 g/mol
- Nitrogen (N): 14.007 g/mol
- Sodium (Na): 22.990 g/mol
- Chlorine (Cl): 35.450 g/mol
The Formula
Molar Mass = Ξ£ (Number of each atom Γ Atomic mass of that element)
Step-by-Step Examples
Example 1: Water (HβO)
- Identify atoms: 2 Γ H, 1 Γ O
- Find atomic masses: H = 1.008, O = 15.999
- Calculate: (2 Γ 1.008) + (1 Γ 15.999)
- = 2.016 + 15.999 = 18.015 g/mol
Example 2: Carbon Dioxide (COβ)
- Atoms: 1 Γ C, 2 Γ O
- Masses: C = 12.011, O = 15.999
- = 12.011 + (2 Γ 15.999) = 12.011 + 31.998 = 44.009 g/mol
Example 3: Glucose (CβHββOβ)
- Atoms: 6 Γ C, 12 Γ H, 6 Γ O
- = (6 Γ 12.011) + (12 Γ 1.008) + (6 Γ 15.999)
- = 72.066 + 12.096 + 95.994 = 180.156 g/mol
Example 4: Sodium Chloride (NaCl)
- Atoms: 1 Γ Na, 1 Γ Cl
- = 22.990 + 35.450 = 58.440 g/mol
Example 5: Sulfuric Acid (HβSOβ)
- Atoms: 2 Γ H, 1 Γ S, 4 Γ O
- S atomic mass = 32.065
- = (2 Γ 1.008) + 32.065 + (4 Γ 15.999)
- = 2.016 + 32.065 + 63.996 = 98.077 g/mol
Handling Parentheses in Formulas
When a formula contains parentheses with a subscript, multiply the subscript by every atom inside:
Calcium hydroxide: Ca(OH)β
- Ca: 1
- O: 1 Γ 2 = 2
- H: 1 Γ 2 = 2
- = 40.078 + (2 Γ 15.999) + (2 Γ 1.008)
- = 40.078 + 31.998 + 2.016 = 74.092 g/mol
Aluminium sulfate: Alβ(SOβ)β
- Al: 2
- S: 1 Γ 3 = 3
- O: 4 Γ 3 = 12
- = (2 Γ 26.982) + (3 Γ 32.065) + (12 Γ 15.999)
- = 53.964 + 96.195 + 191.988 = 342.147 g/mol
Converting Grams to Moles and Back
Moles = Mass (g) Γ· Molar Mass (g/mol)
Mass (g) = Moles Γ Molar Mass (g/mol)
Example: How many moles in 50 g of water?
- Moles = 50 g Γ· 18.015 g/mol = 2.776 mol
Example: What mass is 0.5 mol of glucose?
- Mass = 0.5 mol Γ 180.156 g/mol = 90.078 g
Common Molar Masses to Memorise
| Compound | Formula | Molar Mass |
|---|---|---|
| Water | HβO | 18.015 |
| Carbon dioxide | COβ | 44.009 |
| Glucose | CβHββOβ | 180.156 |
| Sodium chloride | NaCl | 58.440 |
| Ammonia | NHβ | 17.031 |
| Methane | CHβ | 16.043 |
| Ethanol | CβHβ OH | 46.068 |
| Oxygen gas | Oβ | 31.998 |
Why Molar Mass Matters
Molar mass is the key conversion in stoichiometry β it links the symbolic world (chemical equations with mole ratios) to the physical world (what you weigh on a balance). Every yield calculation, every concentration determination, and every limiting reagent problem requires it.